Effect of film formed on the surface of gold during cyanidation on the dissolution rate of gold

In the cyanidation process of gold , impurities can form various films on the surface of gold particles and affect the dissolution rate of gold. The resulting film and its effect on the dissolution rate of gold are as follows:

1. sulfide film     In the cyanide solution, when the sulfur ion concentration reaches 0.5 ppm , the dissolution rate of gold is lowered. This is due to the formation of an insoluble gold sulfide film on the surface of the gold particles which hinders the continued dissolution of gold.

2. Hydrogen peroxide film     When calcium hydroxide is used as a protective base, a calcium peroxide film is formed on the surface of gold to hinder the action of gold and cyanide. This can be thought of as the formation of lime and H 2 O 2 accumulated in solution as follows:

   Ca(OH) 2 +H 2 O 2 → CaO 2 +2H 2 O

3. Oxide film     When ozone is added to the cyanide solution, a brick red gold oxide film is formed on the surface of the gold to reduce the dissolution rate of gold.

4. Insoluble oxide film     Appropriate amount of Pb 2+ has a growth-increasing effect on the dissolution of gold, and when it is excessive, it causes a blocking effect. This is because lead and gold form a primary battery, and gold becomes an anode in the primary battery, so gold is transferred to the solution. Excess Pb 2+ will deposit as an insoluble Pb(CN) 2 film on the surface of gold .

5. Xanthate gold film     When the flotation concentrate is cyanated, the concentration of gold in the cyanide solution exceeds 0.4 ppm , and the dissolution rate of gold decreases. This is due to the formation of a gold film of xanthate on the surface of gold. In order to overcome this adverse effect, in the case of ensuring the flotation recovery rate, the amount of the flotation agent is reduced as much as possible, and the drug is removed before the flotation concentrate is cyanated.

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